@article{ISI:000457067500008,
title = {Singlet Fission in Combinatorial Diketopyrrolopyrrole-Rylene
Supramolecular Films},
author = {Andrew M Levine and Christoph Schierl and Bettina S Basel and Mehroz Ahmed and Braden A Camargo and Dirk M Guldi and Adam B Braunschweig},
doi = {10.1021/acs.jpcc.8b09593},
issn = {1932-7447},
year = {2019},
date = {2019-01-01},
journal = {JOURNAL OF PHYSICAL CHEMISTRY C},
volume = {123},
number = {3},
pages = {1587-1595},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
@article{ISI:000460162900065,
title = {Nanographene favors electronic interactions with an electron acceptor
rather than an electron donor in a planar fused push-pull conjugate},
author = {Michel Volland and Ping Zhou and Leonie Wibmer and Robert Haener and Silvio Decurtins and Shi-Xia Liu and Dirk M Guldi},
doi = {10.1039/c8nr06961a},
issn = {2040-3364},
year = {2019},
date = {2019-01-01},
journal = {NANOSCALE},
volume = {11},
number = {3},
pages = {1437-1441},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
Casillas, Ruben; Adam, Matthias; Coto, Pedro B; Waterloo, Andreas R; Zirzlmeier, Johannes; Reddy, Seelam Rajagopala; Hampel, Frank; McDonald, Robert; Tykwinski, Rik R; Thoss, Michael; Guldi, Dirk M: Intermolecular Singlet Fission in Unsymmetrical Derivatives of Pentacene
in Solution. In: ADVANCED ENERGY MATERIALS, 9 (2), 2019, ISSN: 1614-6832.(Type: Journal Article | Links | BibTeX)
@article{ISI:000457575300001,
title = {Intermolecular Singlet Fission in Unsymmetrical Derivatives of Pentacene
in Solution},
author = {Ruben Casillas and Matthias Adam and Pedro B Coto and Andreas R Waterloo and Johannes Zirzlmeier and Seelam Rajagopala Reddy and Frank Hampel and Robert McDonald and Rik R Tykwinski and Michael Thoss and Dirk M Guldi},
doi = {10.1002/aenm.201802221},
issn = {1614-6832},
year = {2019},
date = {2019-01-01},
journal = {ADVANCED ENERGY MATERIALS},
volume = {9},
number = {2},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
@article{ISI:000455111100021,
title = {Ionic-Liquid Doping Enables High Transconductance, Fast Response Time,
and High Ion Sensitivity in Organic Electrochemical Transistors},
author = {Xihu Wu and Abhijith Surendran and Jieun Ko and Oliver Filonik and Eva M Herzig and Peter Mueller-Buschbaum and Wei Lin Leong},
doi = {10.1002/adma.201805544},
issn = {0935-9648},
year = {2019},
date = {2019-01-01},
journal = {ADVANCED MATERIALS},
volume = {31},
number = {2},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
@article{ISI:000453601400007,
title = {Dithienobenzimidazole-containing conjugated donor-acceptor polymers:
Synthesis and characterization},
author = {Jared D Harris and Markus Stihl and Hans-Werner Schmidt and Kenneth R Carter},
doi = {10.1002/pola.29284},
issn = {0887-624X},
year = {2019},
date = {2019-01-01},
journal = {JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY},
volume = {57},
number = {1},
pages = {60-69},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
@article{C9TC04472H,
title = {Ultrafast intramolecular energy transfer in a nanostructured organosilicon luminophore based on p-terphenyl and 1,4-bis(5-phenyloxazol-2-yl)benzene},
author = {Sergey A Ponomarenko and Nikolay M Surin and Maxim S Skorotetcky and Oleg V Borshchev and Sergey A Pisarev and Evgenia A Svidchenko and Yuriy V Fedorov and Francesc Molins and Tobias Brixner},
url = {http://dx.doi.org/10.1039/C9TC04472H},
doi = {10.1039/C9TC04472H},
year = {2019},
date = {2019-01-01},
journal = {J. Mater. Chem. C},
volume = {7},
pages = {14612-14624},
publisher = {The Royal Society of Chemistry},
abstract = {We report on the first experimental and theoretical investigations of ultrafast intramolecular energy transfer for a novel class of highly luminescent materials – nanostructured organosilicon luminophores (NOLs). For this purpose we designed, synthesized and investigated a NOL, (POPOP)Si2(3Ph-EH)6, consisting of six p-terphenyl (3Ph) donor and 1,4-bis(5-phenyloxazol-2-yl)benzene (POPOP) acceptor luminophores – well-known laser dyes widely used in plastic scintillators as an activator and a spectral shifter, respectively. The NOL shows excellent optical properties – molar absorption coefficient up to 2.6 × 105 L mol−1 cm−1, photoluminescence quantum yield up to 96% and pseudo Stokes shift of 100 nm. Its intramolecular energy transfer efficiency determined from steady-state optical measurements was found to be 93%, while the excitation lifetime was less than 1 ns. For deeper understanding of the processes of intramolecular energy transfer within NOLs, ultrafast spectroscopy investigations of the NOL, model donor and acceptor luminophores were performed for the first time for this class of compounds. It was found that the time constant of the energy transfer from donor to acceptor luminophores within the NOL is τ1 = 105 fs, which is significantly faster than the vibrational relaxation within the donor (ca. 400 fs). Based on these findings, a kinetic scheme of the electronic excitation energy deactivation processes in the NOL was developed. The results obtained not only directly prove that the mechanism of energy transfer within the NOLs is based on Förster resonance energy transfer of the excitation energy from donor to acceptor luminophores, but also highlight the advantages of NOLs and NOL-based materials for future photonics applications – fast and efficient plastic scintillators, scintillating fibers and other spectral shifting optical materials.},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
We report on the first experimental and theoretical investigations of ultrafast intramolecular energy transfer for a novel class of highly luminescent materials – nanostructured organosilicon luminophores (NOLs). For this purpose we designed, synthesized and investigated a NOL, (POPOP)Si2(3Ph-EH)6, consisting of six p-terphenyl (3Ph) donor and 1,4-bis(5-phenyloxazol-2-yl)benzene (POPOP) acceptor luminophores – well-known laser dyes widely used in plastic scintillators as an activator and a spectral shifter, respectively. The NOL shows excellent optical properties – molar absorption coefficient up to 2.6 × 105 L mol−1 cm−1, photoluminescence quantum yield up to 96% and pseudo Stokes shift of 100 nm. Its intramolecular energy transfer efficiency determined from steady-state optical measurements was found to be 93%, while the excitation lifetime was less than 1 ns. For deeper understanding of the processes of intramolecular energy transfer within NOLs, ultrafast spectroscopy investigations of the NOL, model donor and acceptor luminophores were performed for the first time for this class of compounds. It was found that the time constant of the energy transfer from donor to acceptor luminophores within the NOL is τ1 = 105 fs, which is significantly faster than the vibrational relaxation within the donor (ca. 400 fs). Based on these findings, a kinetic scheme of the electronic excitation energy deactivation processes in the NOL was developed. The results obtained not only directly prove that the mechanism of energy transfer within the NOLs is based on Förster resonance energy transfer of the excitation energy from donor to acceptor luminophores, but also highlight the advantages of NOLs and NOL-based materials for future photonics applications – fast and efficient plastic scintillators, scintillating fibers and other spectral shifting optical materials.
@article{ISI:000457067300065b,
title = {Composition Morphology Correlation in PTB7-Th/PC71 BM Blend Films for
Organic Solar Cells},
author = {Lin Song and Weijia Wang and Edoardo Barabino and Dan Yang and Volker Koerstgens and Peng Zhang and Stephan V Roth and Peter Mueller-Buschbaum},
doi = {10.1021/acsami.8b20316},
issn = {1944-8244},
year = {2019},
date = {2019-01-01},
journal = {ACS APPLIED MATERIALS & INTERFACES},
volume = {11},
number = {3},
pages = {3125-3135},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
@article{Hoche2019,
title = {The origin of the solvent dependence of fluorescence quantum yields in dipolar merocyanine dyes},
author = {Joscha Hoche and Alexander Schulz and Lysanne Monika Dietrich and Alexander Humeniuk and Matthias Stolte and David Schmidt and Tobias Brixner and Frank Würthner and Roland Mitric},
doi = {10.1039/c9sc05012d},
year = {2019},
date = {2019-01-01},
journal = {Chemical Science},
volume = {10},
number = {48},
pages = {11013--11022},
publisher = {Royal Society of Chemistry (RSC)},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
@article{Kiermasch2019,
title = {Unravelling steady-state bulk recombination dynamics in thick efficient vacuum-deposited perovskite solar cells by transient methods},
author = {David Kiermasch and Lid ó and Andreas Baumann and Henk J Bolink and Vladimir Dyakonov and Kristofer Tvingstedt},
doi = {10.1039/c9ta04367e},
year = {2019},
date = {2019-01-01},
journal = {Journal of Materials Chemistry A},
volume = {7},
number = {24},
pages = {14712--14722},
publisher = {Royal Society of Chemistry (RSC)},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
@article{Griesbeck2019a,
title = {Tuning the $uppi$-bridge of quadrupolar triarylborane chromophores for one- and two-photon excited fluorescence imaging of lysosomes in live cells},
author = {Stefanie Griesbeck and Evripidis Michail and Chenguang Wang and Hiroaki Ogasawara and Sabine Lorenzen and Lukas Gerstner and Theresa Zang and Jörn Nitsch and Yoshikatsu Sato and Rüdiger Bertermann and Masayasu Taki and Christoph Lambert and Shigehiro Yamaguchi and Todd B Marder},
doi = {10.1039/c9sc00793h},
year = {2019},
date = {2019-01-01},
journal = {Chemical Science},
volume = {10},
number = {20},
pages = {5405--5422},
publisher = {Royal Society of Chemistry (RSC)},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
@article{ISI:000452650200013c,
title = {Fine-tuning of the chemical structure of photoactive materials for
highly efficient organic photovoltaics},
author = {Baobing Fan and Xiaoyan Du and Feng Liu and Wenkai Zhong and Lei Ying and Ruihao Xie and Xiaofeng Tang and Kang An and Jingming Xin and Ning Li and Wei Ma and Christoph J Brabec and Fei Huang and Yong Cao},
doi = {10.1038/s41560-018-0263-4},
issn = {2058-7546},
year = {2018},
date = {2018-12-01},
journal = {NATURE ENERGY},
volume = {3},
number = {12},
pages = {1051-1058},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
@article{ISI:000450456900001c,
title = {A Feynman dispersion correction: a proof of principle for MNDO},
author = {Maximilian Kriebel and Konstantin Weber and Timothy Clark},
doi = {10.1007/s00894-018-3874-6},
issn = {1610-2940},
year = {2018},
date = {2018-12-01},
journal = {JOURNAL OF MOLECULAR MODELING},
volume = {24},
number = {12},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
@article{ISI:000449708500085c,
title = {New synthesized ionic liquid functionalized graphene oxide: Synthesis,
characterization and its nanocomposite with conjugated polymer as
effective electrode materials in an energy storage device},
author = {Farshad Boorboor Ajdari and Elaheh Kowsari and Ali Ehsani and Milan Schorowski and Tayebeh Ameri},
doi = {10.1016/j.electacta.2018.09.177},
issn = {0013-4686},
year = {2018},
date = {2018-12-01},
journal = {ELECTROCHIMICA ACTA},
volume = {292},
pages = {789-804},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
@article{Song_2018c,
title = {Understanding macroscale functionality of metal halide perovskites in terms of nanoscale heterogeneities},
author = {Tze-Bin Song and Ian D Sharp and Carolin M Sutter-Fella},
doi = {10.1088/2515-7655/aaeee5},
year = {2018},
date = {2018-12-01},
journal = {Journal of Physics: Energy},
volume = {1},
number = {1},
pages = {011002},
publisher = {IOP Publishing},
abstract = {Hybrid metal halide perovskites have shown an unprecedented rise as semiconductor building blocks for solar energy conversion and light-emitting applications. Currently, the field moves empirically towards more and more complex chemical compositions, including mixed halide quadruple cation compounds that allow optical properties to be tuned and show promise for better stability. Despite tremendous progress in the field, there is a need for better understanding of mechanisms of efficiency loss and instabilities to facilitate rational optimization of composition. Starting from the device level and then diving into nanoscale properties, we highlight how structural and compositional heterogeneities affect macroscopic optoelectronic characteristics. Furthermore, we provide an overview of some of the advanced spectroscopy and imaging methods that are used to probe disorder and non-uniformities. A unique feature of hybrid halide perovskite compounds is the propensity for these heterogeneities to evolve in space and time under relatively mild illumination and applied electric fields, such as those found within active devices. This introduces an additional challenge for characterization and calls for application of complimentary probes that can aid in correlating the properties of local disorder with macroscopic function, with the ultimate goal of rationally tailoring synthesis towards optimal structures and compositions.},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
Hybrid metal halide perovskites have shown an unprecedented rise as semiconductor building blocks for solar energy conversion and light-emitting applications. Currently, the field moves empirically towards more and more complex chemical compositions, including mixed halide quadruple cation compounds that allow optical properties to be tuned and show promise for better stability. Despite tremendous progress in the field, there is a need for better understanding of mechanisms of efficiency loss and instabilities to facilitate rational optimization of composition. Starting from the device level and then diving into nanoscale properties, we highlight how structural and compositional heterogeneities affect macroscopic optoelectronic characteristics. Furthermore, we provide an overview of some of the advanced spectroscopy and imaging methods that are used to probe disorder and non-uniformities. A unique feature of hybrid halide perovskite compounds is the propensity for these heterogeneities to evolve in space and time under relatively mild illumination and applied electric fields, such as those found within active devices. This introduces an additional challenge for characterization and calls for application of complimentary probes that can aid in correlating the properties of local disorder with macroscopic function, with the ultimate goal of rationally tailoring synthesis towards optimal structures and compositions.
@article{ISI:000456422500005,
title = {Why Tin-Doping Enhances the Efficiency of Hematite Photoanodes for Water Splitting-The Full Picture},
author = {Alexander G Hufnagel and Hamidreza Hajiyani and Siyuan Zhang and Tong Li and Olga Kasian and Baptiste Gault and Benjamin Breitbach and Thomas Bein and Dina Fattakhova-Rohlfing and Christina Scheu and Rossitza Pentcheva},
doi = {10.1002/adfm.201804472},
issn = {1616-301X},
year = {2018},
date = {2018-12-01},
journal = {ADVANCED FUNCTIONAL MATERIALS},
volume = {28},
number = {52},
pages = {1804472},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
@article{ISI:000454567200006,
title = {Capping nido-Nonagermanide Clusters with M-PPh3 and Dynamics in Solution: Synthesis and Structure of closo-[(Me3Si)(3)Si](3)Et[Ge9M](PPh3) (M = Ni, Pt)},
author = {Sabine Frischhut and Felix Kaiser and Wilhelm Klein and Markus Drees and Fritz E Kuehn and Thomas F Faessler},
doi = {10.1021/acs.organomet.8b00459},
issn = {0276-7333},
year = {2018},
date = {2018-12-01},
journal = {ORGANOMETALLICS},
volume = {37},
number = {24},
pages = {4560-4567},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
@article{ISI:000452490800028,
title = {Synergy of light harvesting and energy transfer as well as short-range
charge shift reactions in multicomponent conjugates},
author = {Ettore Fazio and Kim A Winterfeld and Ana Lopez-Perez and Tomas Torres and Dirk M Guldi and Gema de la Torre},
doi = {10.1039/c8nr08438f},
issn = {2040-3364},
year = {2018},
date = {2018-12-01},
journal = {NANOSCALE},
volume = {10},
number = {47},
pages = {22400-22408},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
@article{ISI:000454383400043,
title = {Selective Photocatalytic C-F Borylation of Polyfluoroarenes by Rh/Ni
Dual Catalysis Providing Valuable Fluorinated Arylboronate Esters},
author = {Ya-Ming Tian and Xiao-Ning Guo and Maximilian W Kuntze-Fechner and Ivo Krummenacher and Holger Braunschweig and Udo Radius and Andreas Steffen and Todd B Marder},
doi = {10.1021/jacs.8b09790},
issn = {0002-7863},
year = {2018},
date = {2018-12-01},
journal = {JOURNAL OF THE AMERICAN CHEMICAL SOCIETY},
volume = {140},
number = {50},
pages = {17612-17623},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
@article{ISI:000454216900007,
title = {X-ray study of anisotropically shaped metal halide perovskite nanoparticles in tubular pores},
author = {Janina Melanie Roemer and Stepan Demchyshyn and Anton Boehm and Olof Gutowski and Kilian Frank and Niyazi Serdar Sariciftci and Martin Kaltenbrunner and Bert Nickel},
doi = {10.1063/1.5054271},
issn = {0003-6951},
year = {2018},
date = {2018-12-01},
journal = {APPLIED PHYSICS LETTERS},
volume = {113},
number = {25},
pages = {251901},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
@article{ISI:000453441300003,
title = {Overcoming efficiency and stability limits in water-processing
nanoparticular organic photovoltaics by minimizing microstructure
defects},
author = {Chen Xie and Thomas Heumueller and Wolfgang Gruber and Xiaofeng Tang and Andrej Classen and Isabel Schuldes and Matthew Bidwell and Andreas Spaeth and Rainer H Fink and Tobias Unruh and Iain McCulloch and Ning Li and Christoph J Brabec},
doi = {10.1038/s41467-018-07807-5},
issn = {2041-1723},
year = {2018},
date = {2018-12-01},
journal = {NATURE COMMUNICATIONS},
volume = {9},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
@article{ISI:000487779100001,
title = {Spontaneous Crystallization of Perovskite Nanocrystals in Nonpolar
Organic Solvents: A Versatile Approach for their Shape-Controlled
Synthesis},
author = {He Huang and Yanxiu Li and Yu Tong and En-Ping Yao and Maximilian W Feil and Alexander F Richter and Markus Doblinger and Andrey L Rogach and Jochen Feldmann and Lakshminarayana Polavarapu},
doi = {10.1002/anie.201906862, Early Access Date = SEP 2019},
issn = {1433-7851},
journal = {ANGEWANDTE CHEMIE-INTERNATIONAL EDITION},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
@article{ISI:000495463900001,
title = {Insulating Ag-Polyimide Hybrid Films with a Tunable Dielectric Constant},
author = {Markus Klaus Diether Wiesinger and Till Welzel and Martin Stutzmann},
doi = {10.1002/pssa.201900488, Early Access Date = NOV 2019},
issn = {1862-6300},
journal = {PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
@article{ISI:000494767900001,
title = {Cucurbiturils in supramolecular catalysis},
author = {Sebastian Funk and Juergen Schatz},
doi = {10.1007/s10847-019-00956-0, Early Access Date = NOV 2019},
issn = {1388-3127},
journal = {JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
@article{ISI:000499022000001,
title = {Mixed Organic Ligand Shells: Controlling the Nanoparticle Surface
Morphology toward Tuning the Optoelectronic Properties},
author = {Christian Henkel and Judith E Wittmann and Johannes Traeg and Johannes Will and Lisa M S Stiegler and Peter Strohriegl and Andreas Hirsch and Tobias Unruh and Dirk Zahn and Marcus Halik and Dirk M Guldi},
doi = {10.1002/smll.201903729, Early Access Date = NOV 2019},
issn = {1613-6810},
journal = {SMALL},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
@article{ISI:000498757500001,
title = {Singlet Fission in Pyrene-Fused Azaacene Dimers},
author = {Juan P Mora-Fuentes and Ilias Papadopoulos and Dominik Thiel and Roberto Alvarez-Boto and Diego Cortizo-Lacalle and Timothy Clark and Manuel Melle-Franco and Dirk M Guldi and Aurelio Mateo-Alonso},
doi = {10.1002/anie.201911529, Early Access Date = NOV 2019},
issn = {1433-7851},
journal = {ANGEWANDTE CHEMIE-INTERNATIONAL EDITION},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
@article{Maehringerb,
title = {Energy Efficient Ultrahigh Flux Separation of Oily Pollutants from Water with Superhydrophilic Nanoscale Metal–Organic Framework Architectures},
author = {Andre Mähringer and Matthias Hennemann and Timothy Clark and Thomas Bein and Dana D Medina},
url = {https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.202012428},
doi = {https://doi.org/10.1002/anie.202012428},
journal = {Angewandte Chemie International Edition},
volume = {n/a},
number = {n/a},
abstract = {Abstract The rising demand for clean water for a growing and increasingly urban global population is one of the most urgent issues of our time. Here, we introduce the synthesis of a unique nanoscale architecture of pillar-like Co-CAT-1 metal–organic framework (MOF) crystallites on gold-coated woven stainless steel meshes with large, 50 μm apertures. These nanostructured mesh surfaces feature superhydrophilic and underwater superoleophobic wetting properties, allowing for gravity-driven, highly efficient oil–water separation featuring water fluxes of up to nearly one million L m−2 h−1. Water physisorption experiments reveal the hydrophilic nature of Co-CAT-1 with a total water vapor uptake at room temperature of 470 cm3 g−1. Semiempirical molecular orbital calculations shed light on water affinity of the inner and outer pore surfaces. The MOF-based membranes enable high separation efficiencies for a number of liquids tested, including the notorious water pollutant, crude oil, affording chemical oxygen demand (COD) concentrations below 25 mg L−1 of the effluent. Our results demonstrate the great impact of suitable nanoscale surface architectures as a means of encoding on-surface extreme wetting properties, yielding energy-efficient water-selective large-aperture membranes.},
keywords = {nanostructures, surface chemistry, thin films, vapor-assisted conversion},
pubstate = {published},
tppubtype = {article}
}
Abstract The rising demand for clean water for a growing and increasingly urban global population is one of the most urgent issues of our time. Here, we introduce the synthesis of a unique nanoscale architecture of pillar-like Co-CAT-1 metal–organic framework (MOF) crystallites on gold-coated woven stainless steel meshes with large, 50 μm apertures. These nanostructured mesh surfaces feature superhydrophilic and underwater superoleophobic wetting properties, allowing for gravity-driven, highly efficient oil–water separation featuring water fluxes of up to nearly one million L m−2 h−1. Water physisorption experiments reveal the hydrophilic nature of Co-CAT-1 with a total water vapor uptake at room temperature of 470 cm3 g−1. Semiempirical molecular orbital calculations shed light on water affinity of the inner and outer pore surfaces. The MOF-based membranes enable high separation efficiencies for a number of liquids tested, including the notorious water pollutant, crude oil, affording chemical oxygen demand (COD) concentrations below 25 mg L−1 of the effluent. Our results demonstrate the great impact of suitable nanoscale surface architectures as a means of encoding on-surface extreme wetting properties, yielding energy-efficient water-selective large-aperture membranes.