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pubstate = {published},
tppubtype = {article}
}
@article{ISI:000495463900001,
title = {Insulating Ag-Polyimide Hybrid Films with a Tunable Dielectric Constant},
author = {Markus Klaus Diether Wiesinger and Till Welzel and Martin Stutzmann},
doi = {10.1002/pssa.201900488, Early Access Date = NOV 2019},
issn = {1862-6300},
journal = {PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
@article{ISI:000494767900001,
title = {Cucurbiturils in supramolecular catalysis},
author = {Sebastian Funk and Juergen Schatz},
doi = {10.1007/s10847-019-00956-0, Early Access Date = NOV 2019},
issn = {1388-3127},
journal = {JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
@article{ISI:000499022000001,
title = {Mixed Organic Ligand Shells: Controlling the Nanoparticle Surface
Morphology toward Tuning the Optoelectronic Properties},
author = {Christian Henkel and Judith E Wittmann and Johannes Traeg and Johannes Will and Lisa M S Stiegler and Peter Strohriegl and Andreas Hirsch and Tobias Unruh and Dirk Zahn and Marcus Halik and Dirk M Guldi},
doi = {10.1002/smll.201903729, Early Access Date = NOV 2019},
issn = {1613-6810},
journal = {SMALL},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
@article{ISI:000498757500001,
title = {Singlet Fission in Pyrene-Fused Azaacene Dimers},
author = {Juan P Mora-Fuentes and Ilias Papadopoulos and Dominik Thiel and Roberto Alvarez-Boto and Diego Cortizo-Lacalle and Timothy Clark and Manuel Melle-Franco and Dirk M Guldi and Aurelio Mateo-Alonso},
doi = {10.1002/anie.201911529, Early Access Date = NOV 2019},
issn = {1433-7851},
journal = {ANGEWANDTE CHEMIE-INTERNATIONAL EDITION},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
@article{Maehringerb,
title = {Energy Efficient Ultrahigh Flux Separation of Oily Pollutants from Water with Superhydrophilic Nanoscale Metal–Organic Framework Architectures},
author = {Andre Mähringer and Matthias Hennemann and Timothy Clark and Thomas Bein and Dana D Medina},
url = {https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.202012428},
doi = {https://doi.org/10.1002/anie.202012428},
journal = {Angewandte Chemie International Edition},
volume = {n/a},
number = {n/a},
abstract = {Abstract The rising demand for clean water for a growing and increasingly urban global population is one of the most urgent issues of our time. Here, we introduce the synthesis of a unique nanoscale architecture of pillar-like Co-CAT-1 metal–organic framework (MOF) crystallites on gold-coated woven stainless steel meshes with large, 50 μm apertures. These nanostructured mesh surfaces feature superhydrophilic and underwater superoleophobic wetting properties, allowing for gravity-driven, highly efficient oil–water separation featuring water fluxes of up to nearly one million L m−2 h−1. Water physisorption experiments reveal the hydrophilic nature of Co-CAT-1 with a total water vapor uptake at room temperature of 470 cm3 g−1. Semiempirical molecular orbital calculations shed light on water affinity of the inner and outer pore surfaces. The MOF-based membranes enable high separation efficiencies for a number of liquids tested, including the notorious water pollutant, crude oil, affording chemical oxygen demand (COD) concentrations below 25 mg L−1 of the effluent. Our results demonstrate the great impact of suitable nanoscale surface architectures as a means of encoding on-surface extreme wetting properties, yielding energy-efficient water-selective large-aperture membranes.},
keywords = {nanostructures, surface chemistry, thin films, vapor-assisted conversion},
pubstate = {published},
tppubtype = {article}
}
Abstract The rising demand for clean water for a growing and increasingly urban global population is one of the most urgent issues of our time. Here, we introduce the synthesis of a unique nanoscale architecture of pillar-like Co-CAT-1 metal–organic framework (MOF) crystallites on gold-coated woven stainless steel meshes with large, 50 μm apertures. These nanostructured mesh surfaces feature superhydrophilic and underwater superoleophobic wetting properties, allowing for gravity-driven, highly efficient oil–water separation featuring water fluxes of up to nearly one million L m−2 h−1. Water physisorption experiments reveal the hydrophilic nature of Co-CAT-1 with a total water vapor uptake at room temperature of 470 cm3 g−1. Semiempirical molecular orbital calculations shed light on water affinity of the inner and outer pore surfaces. The MOF-based membranes enable high separation efficiencies for a number of liquids tested, including the notorious water pollutant, crude oil, affording chemical oxygen demand (COD) concentrations below 25 mg L−1 of the effluent. Our results demonstrate the great impact of suitable nanoscale surface architectures as a means of encoding on-surface extreme wetting properties, yielding energy-efficient water-selective large-aperture membranes.