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| 1. | Walther, Luis; Radacki, Krzysztof; Dewhurst, Rian D; Bertermann, Rüdiger; Finze, Maik; Braunschweig, Holger: All-Inorganic sp-Chain Ligands: Isoelectronic B/N Analogues of E. O. Fischer's Alkynylcarbynes. In: Angewandte Chemie - International Edition, 63 (30), 2024, ISSN: 14337851, (Cited by: 0). (Type: Journal Article | Abstract | Links | BibTeX) @article{Walther2024, title = {All-Inorganic sp-Chain Ligands: Isoelectronic B/N Analogues of E. O. Fischer's Alkynylcarbynes}, author = {Luis Walther and Krzysztof Radacki and Rian D Dewhurst and Rüdiger Bertermann and Maik Finze and Holger Braunschweig}, url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-85196487754&doi=10.1002%2fanie.202404930&partnerID=40&md5=a3b7b1e54e914af660cef048fba965c1}, doi = {10.1002/anie.202404930}, issn = {14337851}, year = {2024}, date = {2024-01-01}, journal = {Angewandte Chemie - International Edition}, volume = {63}, number = {30}, publisher = {John Wiley and Sons Inc}, abstract = {Borylation of a tungsten-bound N2 ligand and halide abstraction provides access to a cationic complex with an unprecedented linear NNBR ligand. This complex undergoes [3+2] cycloaddition with azides, and an unexpected chain-extension reaction with an iminoborane, leading to a complex with a five-atom B/N chain. These two [NNBR]-containing complexes, inorganic analogues of E. O. Fischer's alkynylcarbynes, are very rare examples of molecules containing all-inorganic chains of sp-hybridized atoms. © 2024 Wiley-VCH GmbH.}, note = {Cited by: 0}, keywords = {}, pubstate = {published}, tppubtype = {article} } Borylation of a tungsten-bound N2 ligand and halide abstraction provides access to a cationic complex with an unprecedented linear NNBR ligand. This complex undergoes [3+2] cycloaddition with azides, and an unexpected chain-extension reaction with an iminoborane, leading to a complex with a five-atom B/N chain. These two [NNBR]-containing complexes, inorganic analogues of E. O. Fischer's alkynylcarbynes, are very rare examples of molecules containing all-inorganic chains of sp-hybridized atoms. © 2024 Wiley-VCH GmbH. |
References (last update: Sept. 23, 2024):
2024 |
Walther, Luis; Radacki, Krzysztof; Dewhurst, Rian D; Bertermann, Rüdiger; Finze, Maik; Braunschweig, Holger All-Inorganic sp-Chain Ligands: Isoelectronic B/N Analogues of E. O. Fischer's Alkynylcarbynes Journal Article Angewandte Chemie - International Edition, 63 (30), 2024, ISSN: 14337851, (Cited by: 0). Abstract | Links | BibTeX | Tags: azide; boron; halide; ligand; nanowire; tungsten; Alkynylcarbene; Borylation; Cationic complexes; Diazenido complex; Halide abstraction; Inorganics; Isoelectronics; Molecular wires; Sp chains; [3+2]-cycloaddition; article; borylation; case report; cycloaddition; Diels Alder reaction; Ligands @article{Walther2024, title = {All-Inorganic sp-Chain Ligands: Isoelectronic B/N Analogues of E. O. Fischer's Alkynylcarbynes}, author = {Luis Walther and Krzysztof Radacki and Rian D Dewhurst and Rüdiger Bertermann and Maik Finze and Holger Braunschweig}, url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-85196487754&doi=10.1002%2fanie.202404930&partnerID=40&md5=a3b7b1e54e914af660cef048fba965c1}, doi = {10.1002/anie.202404930}, issn = {14337851}, year = {2024}, date = {2024-01-01}, journal = {Angewandte Chemie - International Edition}, volume = {63}, number = {30}, publisher = {John Wiley and Sons Inc}, abstract = {Borylation of a tungsten-bound N2 ligand and halide abstraction provides access to a cationic complex with an unprecedented linear NNBR ligand. This complex undergoes [3+2] cycloaddition with azides, and an unexpected chain-extension reaction with an iminoborane, leading to a complex with a five-atom B/N chain. These two [NNBR]-containing complexes, inorganic analogues of E. O. Fischer's alkynylcarbynes, are very rare examples of molecules containing all-inorganic chains of sp-hybridized atoms. © 2024 Wiley-VCH GmbH.}, note = {Cited by: 0}, keywords = {azide; boron; halide; ligand; nanowire; tungsten; Alkynylcarbene; Borylation; Cationic complexes; Diazenido complex; Halide abstraction; Inorganics; Isoelectronics; Molecular wires; Sp chains; [3+2]-cycloaddition; article; borylation; case report; cycloaddition; Diels Alder reaction; Ligands}, pubstate = {published}, tppubtype = {article} } Borylation of a tungsten-bound N2 ligand and halide abstraction provides access to a cationic complex with an unprecedented linear NNBR ligand. This complex undergoes [3+2] cycloaddition with azides, and an unexpected chain-extension reaction with an iminoborane, leading to a complex with a five-atom B/N chain. These two [NNBR]-containing complexes, inorganic analogues of E. O. Fischer's alkynylcarbynes, are very rare examples of molecules containing all-inorganic chains of sp-hybridized atoms. © 2024 Wiley-VCH GmbH. |